There are several herbicides made from natural ingredients. Those that contain clove oil (eugenol) give the best control of young broadleaf weeds. Products containing acetic acid, often in combination with citric acid, do a good job on young grasses. Some products contain both clove oil and acetic acid, so they are useful for a broad variety of weeds.
Soap-based herbicides dehydrate leaves by cutting through their protective layer of cutin. All of these types of organic herbicides work best on young weeds and pose only a temporary setback to well-rooted perennial weeds. To minimize damage to neighboring plants, spray only in dry, still weather. To maximize effectiveness, spray young weeds when temperatures are above 70 degrees F and the sun is shining brightly. Be aware that repeated applications of a product containing acetic acid (which is very strong vinegar) can lower the soil's pH, making it more acidic.