You should remove any weeds in the unsodded areas and rototill the soil lightly. Then you can either plant centipede from seed or sod. Centipede doesn't like to be fertilized much so only put 1/2 pound of actual nitrogen per 1000 square feet. This would be for example about 3 pounds of 15-5-10 or similar product. Avoid using broadleaf weed control products when temperatures are in the 80's and above as they can stress the centipede turf.
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