I think the buffering thing is only relevant if you water with (RO) purified water, otherwise your tap water probably has enough minerals in it to make buffering irrelevant. There are theoretically some brands of coir that still have salt in them, presumably to save a step in manufacturing, but I don't know what reputable nursery would stock them. Any product for horticultural use should be prerinsed.
To acidify my water I use a product called "Acid Buffer" (Seachem brand) which is bisulfate with Mg/Ca as the cation. You can use a wide variety of acids for this purpose (some of them available as pool chemicals, others like mine sold "for planted aquaria")... the important thing is that the acid be free of sodium and ideally it should have minimal bioactivity (like the sulfate produced by mine). Some people use household (cane) vinegar. Whatever works for you, just be sure you test the pH of your water afterwards so you know you didn't overshoot. Adding acid without measuring the pH is a bad idea, at least until you know precisely how much to add.