If you know what they are and when they will be germinating, disturb/till the soil at that time. It will interrupt the root formation of most of them. Or will you have new seeds in by then? If so, disturb it now. Some might still stick around, but messing with the soil will thin them. Or, turn the soil completely so the old seeds are buried too deeply to germinate. Any pre-emergent product could kill the new seeds and probably isn't a good idea around your fish pond, either.