I also use sulfur to help acidify soil, but it doesn't last forever. It's not the sulfur element that acidifies, rather, it's the compounds that sulfur forms; sulfuric acid is one of them. Many (all?) of these compounds are mobile in the soil and can leach out. Changing the pH of your soil is a lot trickier than you think, and the tendency is always to overdo it, so be careful.
Compost is a most wonderful thing. It improve the soil structure, soil flora and soil composition in so many ways. It is also a great pH buffer with the tendency to keep the soil pH at or near its own pH. "Its own pH" can vary quite a bit depending what it is made from, but is usually about 6-6.5.
If you are talking about using pH Down for swimming pools in soil, I don't know. But I would never use it unless I researched its mode of action and could apply that (somehow) to soil application. I would guess that being very soluble in water, it would leach out of the soil quickly, so it would not be a good soil acidifier.