Karen, this year I started to spray in February. I do mostly the areas where blackspot has been a problem, and roses that are most affected by the disease. We get a lot of UV light here, so I know I need to spray periodically. I think I've done it three times altogether this year. I'm actually pretty surprised at how well it has been working so far this season.
I began using it last year when I had a BS outbreak that touched a few dozen roses. I'd say it brought things under control fairly quickly, a couple of weeks. I'll know a lot more once I see how the garden makes it through the monsoons in July and August. BTW, I also treat the mulch around the roses because I know BS spores overwinter there. One of the things I love is that I do not need to 'wet every surface' to get control; I just have to get the Actinovate bacteria kinda close to the BS fungus, and they seem to find it. Of course, when I see BS on a leaf, I do my best to hit it with the fungicide.
I have a number of herbaceous peonies; but they are pretty young and I've not yet had serious fungal problems. Also we have really dry sping weather here.
I hope you find something that works. It's heartbreaking to invest a lot of time and money in plants only to lose them to one kind of blight or another.