PPal - Not so. Sea shells just change the pH. Too much calcium raises the pH. Most aquarium fish available today can tolerate a very VERY wide range of pH (from 6.2 to 8.2), but in order for them to be "optimal" the fish should be kept in the pH that they're from in the wild. For instance, neon tetras are from the Amazon river. The pH there is very low, between 5.5 & 6.5. However, they live quite happily in "neutral" pH of around 7 to 7.5. Higher than 7.5 & they don't thrive as well. African cichlids from the 3 Great Lakes of Africa are all very high pH needing fish. For my Africans, I use either puka shell (crushed oyster shell) or crushed coral for the base. Their pH is at least 8.0, but if I wanted to breed them (which I do NOT 'cuz they breed faster than bunnies), I'd raise it to 8.5. All depends on the fish.
A single scallop shell decoration in a 10gal won't affect the water a heck of a lot.. a negligible amount. Now if you put in a huge conch shell in a 10 gal tank, after about 6 months it could change the water up to 2 points on the pH scale. It also depends on your native water. My water here in CO is naturally high in pH due to it coming from the mountains. Straight out of the tap it's already about 7.8. If I wanted to breed discus or angels, I'd have to either use RO water or use a softener (or there's chemicals to lower pH, but I don't like using chems). But, of course, one thing you have to look at are the shells themselves. If you went to the beach & picked them up, I'd soak 'em in a 5gal bucket w/1 cup kosher salt mixed in for about a week or so before dumping them in your tank 'cuz of the pollution from the ocean. If you're buying shells, make sure they're not lacquered. Do NOT use dried sea critters (starfish/sponges) as aquarium decor as they'll dissolve quickly & make a NASTY mess, plus possibly kill your fish & contaminate the tank. Decor in fish stores for the most part are OK to use. What I do is, if I'm not sure, is the finger-nail test. If I can scrape parts off with my fingernail, it's not gonna be fish safe (paint flaking off). And since most decor is make in China, who knows what chems they used in making the decor. Ceramic decor is best if you can find it. They're usually older, but they're the best. I personally love glass blocks as decoration. Melted Coke bottles make great decor (look at this picture in the background, you can see 3 melted glass blobs as decor in front of the "Jaws")