It's definitely a nicotiana but I'm not sure on the variety.
The small plant to the left of it is a fat-hen (also called Goosefoot) and is an edible weed. It's related to spinach and is good for you. Eat the young tips raw for the best experience.
Name: Lee Anne Stark Brockville, Ontario, Canada (Zone 5a) Perpetually happy!
I was gonna say nicotianna too but I've never seen one with skinny leaves. Nicotianna scent is strongest at night. i plant them everywhere for a nice night scent wafting in the windows.