Welcome.
A tall fence all the way around..and I would dig a trench and lay about 6-8 inches minimum under the earth ..rabbits..moles ...and voles ( research to see how deep the moles may go in winter ) If the deer can get a running start..make it tall, although they can jump pretty high from a stationary position. I am sure there are sprays that would be fine in the organic garden but to me..a fence is more dependable and once erected less work.