dyzzypyxxy said:I know Chris. The hard water deposits on the leaves of your orchids was most likely a good part made of calcium from your tap water. That's why I'm saying I don't think you need to be buying something to "add" calcium when you have it right there in your tap water. Maybe give them a douse with the hose once a month, for a shot of calcium from the tap water.
The potassium nitrate IS fertilizer too, so you are feeding your Phals very lightly every time you mist them with it. It just sounds to me as if you aren't letting them dry out very much between all the misting and watering you are doing. Try leaving them to dry out at least a couple of days a week and see what happens?
The number one cause of death in orchids is over-watering, remember.