I prefer them after a good frost or two on them as they'll sweeten up a bit but have friends who eat them year round. I think you should go ahead and pick some of the lower leaves on some of the plants and give 'em a try now. You can still have plenty left in the garden to try when cooler weather sets in.
VERY nice looking garden, by the way. You've been busy! Congrats!
Shoe (collard green lover, with smoked ham or ham hock or salted fat back or my favorite, smoked turkey leg in the pot~!!)