If you're catching rainwater off a roof via a gutter, there's already some bird poop (and possibly dog poop, if you have crows, magpies, etc. that carry it to the roof to pick it apart). So the water in your tank might already have a load of bacteria. Adding fertilizer to that seems like a risk. If it's misted on fruit and edible leaves it might contaminate them. In any event, you should wash all produce in contact with collected rainwater thoroughly before using.
I was planning to catch rainwater off a roof to fill tanks in my greenhouse, until I noticed the magpies picking apart dog poop there. Alas! I still catch rain, but use it to water the outdoor garden, shrubs, etc.